Reactions of trimethylsilyl isocyanate with alcohols and phenols

Mono- and diphenols add to trimethyl isocyanate on heating to give the corresponding aryl urethanes. Ethanol reacts with trimethylsilyl isocyanate to give ethyl urethane and ethyl allophanate in a ratio determined by reaction conditions.

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 71; no. 3; pp. 325 - 326
Main Authors Pudovik, MA, Krepysheva, NE, Kharitonov, DI, Pudovik, AN
Format Journal Article
LanguageEnglish
Published NEW YORK MAIK NAUKA/INTERPERIODICA 01.03.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:Mono- and diphenols add to trimethyl isocyanate on heating to give the corresponding aryl urethanes. Ethanol reacts with trimethylsilyl isocyanate to give ethyl urethane and ethyl allophanate in a ratio determined by reaction conditions.
ISSN:1070-3632
DOI:10.1023/A:1012388413957