Crystal structure-reactivity relationships in the solid state photochemistry of 2,4,6-triisopropylthiobenzophenone: C=O...H versus C=S...H abstraction geometry
X-ray crystal structure solid state photoreactivity correlations are reported for 2,4,6-triisopropylthiobenzophenone (1a) and its p-methoxy derivative 1b. The results reveal interesting differences in the geometry of gamma-hydrogen atom abstraction for ketones and thiones.
Saved in:
Published in | Tetrahedron letters Vol. 37; no. 13; pp. 2125 - 2128 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier
25.03.1996
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | X-ray crystal structure solid state photoreactivity correlations are reported for 2,4,6-triisopropylthiobenzophenone (1a) and its p-methoxy derivative 1b. The results reveal interesting differences in the geometry of gamma-hydrogen atom abstraction for ketones and thiones. |
---|---|
ISSN: | 0040-4039 1873-3581 |
DOI: | 10.1016/0040-4039(96)00232-8 |