Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts X-ray crystal structures of two [(diphosphine)Pd(NCMe)(OH2)](2+)[OTf](2)(-) complexes

A series of cationic (diphosphine)palladium(II) complexes have been prepared and fully characterized, including two crystal structures. These complexes were evaluated as catalysts for the hydroamination of acyclic alkenes. The reactivity of the catalysts is dependent on the nature of the diphosphine...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 665; no. 1-2; pp. 250 - 257
Main Authors Li, KL, Horton, PN, Hursthouse, MB, Hii, KK
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier 03.01.2003
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
ALKENES
AMINATION
AMINES
INTERMOLECULAR HYDROAMINATION
palladium
diphosphine
hydroamination
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Summary:A series of cationic (diphosphine)palladium(II) complexes have been prepared and fully characterized, including two crystal structures. These complexes were evaluated as catalysts for the hydroamination of acyclic alkenes. The reactivity of the catalysts is dependent on the nature of the diphosphine ligand and the substituents on the amine and alkene substrates. (C) 2002 Elsevier Science B.V. All rights reserved.
ISSN:0022-328X
DOI:10.1016/S0022-328X(02)02138-1