Recent Progress in Transition Metal-Catalyzed Addition Reactions of H–P(O) Compounds with Unsaturated Carbon Linkages

Organophosphorus compounds are playing important roles in our daily life covering a wide range of applications from medicinal use to flame-retardant materials. Although classical synthetic methodologies are still used to synthesize them, the addition reactions of H–P(O) compounds such as H-phosphona...

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Bibliographic Details
Published inHydrofunctionalization pp. 167 - 201
Main Author Tanaka, Masato
Format Book Chapter
LanguageEnglish
Published Berlin, Heidelberg Springer Berlin Heidelberg 16.11.2011
SeriesTopics in Organometallic Chemistry
Subjects
Hydrophosphinylation
Hydrophosphorylation
phosphinate
phosphonate
Secondary phosphine oxide
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Summary:Organophosphorus compounds are playing important roles in our daily life covering a wide range of applications from medicinal use to flame-retardant materials. Although classical synthetic methodologies are still used to synthesize them, the addition reactions of H–P(O) compounds such as H-phosphonates, H-phosphinates, and sec-phosphine oxides have been developed to partially replace the classical methods and are envisioned to be an indispensable tool in the near future. This chapter intends basically to provide recent progress in the field, but not a full scope on the reaction since the same subject was already written by the author in 2004.
ISBN:9783642337345
3642337341
ISSN:1436-6002
1616-8534
DOI:10.1007/3418_2011_20