Development of the He mass spectrometric low-level tritium analytical facility at the IAEA

• Published in: Journal of analytical atomic spectrometry Vol. 37; no. 12; pp. 252 - 259
• Main Authors: Mabry, Jennifer, Romeo, Nicolo, Kainz, Gerhard, Copia, Lorenzo, Masuda, Harue, Matsumoto, Takuya
• Format: Journal Article
• Published: 30.11.2022
• ISSN: 0267-9477; 1364-5544
• DOI: 10.1039/d2ja00173j

Here we present a mass spectrometric system specifically developed for the analysis of ultra-low-level tritium by the 3 He ingrowth method. The system was designed and developed in the Isotope Hydrology Laboratory of the International Atomic Energy Agency and consists of an off-line water degassing unit to remove pre-existing 3 He from sample water and a mass spectrometer system (Thermo Fisher Helix SFT) with a gas purification and separation system. The mass spectrometer system is equipped with a gas pipette system that inlets calibrated amounts of 3 He (99.995% 3 He spike) to accurately calibrate the mass spectrometer's sensitivity. The procedural blank level of 3 He in our system is extremely low and on the order of 10 −17 cm 3 STP, which enables us to quantify tritium in water samples (100 cm 3 ) as low as 0.05 TU with an ingrowth time of 2 months. Quantification of even lower tritium levels are possible by loading more water and/or by increasing the ingrowth time ( e.g. , 0.01 TU with 400 cm 3 water stored for 4 months). We analysed a set of water samples from the Tritium Intercomparison Exercise by IAEA (TRIC 2018) and confirmed that our data were consistent with the expected values. We have also confirmed that our analysis of natural groundwater samples agree well with the data obtained by the conventional liquid scintillation counting (LSC) method. This work will describe a system to quantify ultra-low-level tritium concentrations in ∼100 mL water samples. Tritium decays into 3 He, thus we can take advantage of high sensitivity noble gas mass spectrometry.