High temperature Fe() spin crossover behaviours in three unprecedented Fe-M-Fe (M = Fe, Cd) linear trinuclear complexes

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions. An azo-based ligand of azotet...

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Published inInorganic chemistry frontiers Vol. 7; no. 7; pp. 1526 - 1531
Main Authors Ouyang, Zhi-Jian, Mo, Xiao-Ying, Yang, Meng, Zhong, Li, Chen, Wen-Bin, Gao, Song, Dong, Wen
Format Journal Article
LanguageEnglish
Published 07.04.2020
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Summary:An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions. An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
1911665
1911663
1911662
and
,
Electronic supplementary information (ESI) available: Crystallographic data and refinement parameters, additional structural figures, and Raman and EPR patterns. CCDC
10.1039/c9qi01560d
ISSN:2052-1553
DOI:10.1039/c9qi01560d