Models of the low-spin iron(III) hydroperoxide intermediate of heme oxygenase: Magnetic resonance evidence for thermodynamic stabilization of the dxy electronic state at ambient temperatures

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 124; no. 21; pp. 6077 - 6089
Main Authors RIVERA, Mario, CAIGNAN, Gregori A, ASTASHKIN, Andrei V, RAITSIMRING, Arnold M, SHOKHIREVA, Tatjana Kh, WALKER, F. Ann
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 20.05.2002
Subjects
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
General. Theory
Thermodynamics
Iron III
Models
Magnetic resonance
Heme
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ISSN:0002-7863
1520-5126
DOI:10.1021/ja017334o