Carbon-skeletal [1,2] anionic and radical sigmatropic rearrangements: group migratory aptitudes as a probe of charge type in the 1,2-shifts of β-phenyl-β-(2-pyridyl)- and β-phenyl-β-(4-pyridyl)ethyl systems

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Bibliographic Details
Published inJournal of organic chemistry Vol. 52; no. 20; pp. 4427 - 4437
Main Authors EISCH, J. J, KOVACS, C. A, CHOBE, P, BOLESLAWSKI, M. P
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.10.1987
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Reaction intermediate
Sigmatropic reaction
Chemical rearrangement
Frontier orbital
Nitrogen heterocycle
Theoretical study
Lithium
Alkali metal
Organic radical anion
Spiran
Chemical reduction
Hueckel method
Sodium
Six membered ring
Benzenic compound
Wagner Meerwein rearrangement
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ISSN:0022-3263
1520-6904
DOI:10.1021/jo00229a001