Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) reaction sequence. Reversible CO addition to a trinuclear species without rupture of a metal-metal bond. Molecular structure of [1,4-dicyclohexyl-1,4-diaza-1,3-butadiene]nonacarbonyltriruthenium, Ru3(CO)9(c-Hx-DAB): a unique 50e trinuclear compound with two elongated Ru-Ru bonds

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Bibliographic Details
Published inInorganic chemistry Vol. 24; no. 4; pp. 518 - 525
Main Authors KEIJSPER, J, POLM, L. H, VAN KOTEN, G, VRIEZE, K, SEIGNETTE, F. A. B, STAM, C. H
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 1985
Subjects
Carbonyl and nitrosyl compounds, and their complexes
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Physics
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Schiff base
Molecular structure
Trinuclear complex
Metal metal bond
Transition metal Compounds
Organic ligand
Ruthenium Carbonyl Complexes
Experimental study
X ray diffraction
Inorganic compound
Crystalline structure
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic00198a018