ChemInform Abstract: Fragment Couplings via CO2 Extrusion—Recombination: Expansion of a Classic Bond‐Forming Strategy via Metallaphotoredox

The metallaphotoredox‐catalyzed decarboxylation—recombination of in situ formed mixed anhydrides gives rise to a variety of ketones (III) and (VI) in moderate to high yields.

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Bibliographic Details
Published inChemInform Vol. 47; no. 9; p. no
Main Authors Le, Chi Chip, MacMillan, David W. C.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY‐VCH Verlag 01.02.2016
Wiley Subscription Services, Inc
Subjects
catalysis, phase‐transfer catalysis
decarboxylation
Expansion
photochemistry, radiation chemistry, chemoluminescence
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Summary:The metallaphotoredox‐catalyzed decarboxylation—recombination of in situ formed mixed anhydrides gives rise to a variety of ketones (III) and (VI) in moderate to high yields.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201609044