Synthesis and Characterization of HgII/Se/CuI Multinuclear Compounds from Mercury(II) Bis(p‐aminobenzeneselenolate) – Hg(SeC6H4NH2‐p)2

In this paper we explore an amino functionalized selenolate unit for the synthesis of new multinuclear compounds with promising interesting properties and potential precursors of semiconductors. We present for the first time the X‐ray crystallographic structure of [Hg(SeC6H4NH2)2]2·diox (1·diox) and...

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Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 645; no. 5; pp. 544 - 550
Main Authors Bublitz, Fabricio, de Azevedo Mello, Melina, Cocco Durigon, Daniele, Dornelles da Silva, Felipe, Hennemann, Artur Luis, Schulz Lang, Ernesto
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 15.03.2019
Subjects
Copper
Crystal structure
Crystallography
Mercury
Mercury (metal)
Mercury compounds
NMR
Nuclear magnetic resonance
p‐Aminobenzeneselenolate
Reflectance
Selenium
Synthesis
Ternary nanoclusters
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Summary:In this paper we explore an amino functionalized selenolate unit for the synthesis of new multinuclear compounds with promising interesting properties and potential precursors of semiconductors. We present for the first time the X‐ray crystallographic structure of [Hg(SeC6H4NH2)2]2·diox (1·diox) and its copper(I) derivatives: HgCu2X2(SeC6H4NH2)2(PPh3)4·4diox [X = Br (2·4diox) and I (3·4diox)]. The compounds 1 and 2, 3 can be considered as the starting material and intermediates, respectively, for the synthesis of ternary HgII/Se/CuI nanoclusters. We also provide IR and NMR spectroscopic data and evaluate the optical features of these compounds by difuse reflectance UV/Vis spectroscopy.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201800503