PORPHYRINS FOR CONTROLLED RADICAL POLYMERIZATION OF VINYL MONOMERS

The influence of various porphyrins and their metal complexes, which differ in ligand environment and nature of center metal atom, on kinetic features of radical polymerization of vinyl monomers, initiated by azo-bis-isobutyronitrile or benzoyl peroxide and on molecular weight characteristics of obt...

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Bibliographic Details
Published inJournal of characterization and development of novel materials Vol. 6; no. 2; p. 105
Main Authors Islamova, R M, Nazarova, S V, Koifman, O I
Format Journal Article
LanguageEnglish
Published Hauppauge Nova Science Publishers, Inc 01.04.2014
Subjects
Atomic properties
Benzoyl peroxide
Chromatography
Free radicals
Ligands
Molecular weight
Monomers
Poisoning
Polymerization
Polymers
Porphyrins
Radicals
Regularization methods
Titanium
Zirconium
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Summary:The influence of various porphyrins and their metal complexes, which differ in ligand environment and nature of center metal atom, on kinetic features of radical polymerization of vinyl monomers, initiated by azo-bis-isobutyronitrile or benzoyl peroxide and on molecular weight characteristics of obtained polymers was studied. Feasible polymerization schemes were proposed.
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ISSN:1937-7975