Na2MoO(2-δ)F(4+δ)--a perovskite with a unique combination of atomic orderings and octahedral tilts
Na2MoO2-δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.
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Published in | Chemical communications (Cambridge, England) Vol. 51; no. 84; pp. 15469 - 15471 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
28.10.2015
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Online Access | Get full text |
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Summary: | Na2MoO2-δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1364-548X |
DOI: | 10.1039/c5cc05446j |