Na2MoO(2-δ)F(4+δ)--a perovskite with a unique combination of atomic orderings and octahedral tilts

Na2MoO2-δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 84; pp. 15469 - 15471
Main Authors Ishikawa, Hajime, Munaò, Irene, Bode, Bela E, Hiroi, Zenji, Lightfoot, Philip
Format Journal Article
LanguageEnglish
Published England 28.10.2015
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Summary:Na2MoO2-δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.
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ISSN:1364-548X
DOI:10.1039/c5cc05446j