Self-association based on orthogonal C=O...C=O interactions in the solid and liquid state

A network of orthogonal C=O...C=O interactions was identified in the X-ray crystal structure of an alpha,alpha-difluorocyclopentanone derivative. This finding inspired investigations of self-association driven by these weak dipolar interactions in apolar solvents, which was proven by (1)H NMR spectr...

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Published inChemical communications (Cambridge, England) Vol. 46; no. 1; pp. 67 - 69
Main Authors Fäh, Christoph, Hardegger, Leo A, Ebert, Marc-Olivier, Schweizer, W Bernd, Diederich, François
Format Journal Article
LanguageEnglish
Published England 07.01.2010
Subjects
Crystallography, X-Ray
Cyclopentanes - chemistry
Ketones - chemistry
Magnetic Resonance Spectroscopy
Molecular Conformation
Thermodynamics
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Summary:A network of orthogonal C=O...C=O interactions was identified in the X-ray crystal structure of an alpha,alpha-difluorocyclopentanone derivative. This finding inspired investigations of self-association driven by these weak dipolar interactions in apolar solvents, which was proven by (1)H NMR spectroscopy.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1364-548X
DOI:10.1039/b912721f