1lambda(4),4lambda(4),8lambda(4),11lambda(4)-Tetrathiacyclotetradecane-1,4,7,10-tetraylidenetetraaminium tetrakis(2,4,6-trimethylbenzenesulfonate)
Investigations of the reactivity of the thio-crown [14]aneS(4) (1,4,8,11-tetrathiacyclotetradecane) towards the aminating agent o-mesitylsulfonylhydroxylamine have lead to the crystallization of 1lambda(4),4lambda(4),8lambda(4),11lambda(4)-tetrathiacyclotetradecane-1,4,7,10-tetraylidenetetraaminium...
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Published in | Acta crystallographica. Section C, Crystal structure communications Vol. 61; no. Pt 6; pp. o411 - o413 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
United States
01.06.2005
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Online Access | Get full text |
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Summary: | Investigations of the reactivity of the thio-crown [14]aneS(4) (1,4,8,11-tetrathiacyclotetradecane) towards the aminating agent o-mesitylsulfonylhydroxylamine have lead to the crystallization of 1lambda(4),4lambda(4),8lambda(4),11lambda(4)-tetrathiacyclotetradecane-1,4,7,10-tetraylidenetetraaminium tetrakis(2,4,6-trimethylbenzenesulfonate), C10H28N4S(4)4+.4C9H11O3S-. The compound crystallizes in a centrosymmetric space group, with half a formula unit in the asymmetric unit. All S atoms within the cationic component are aminated, with the four NH(2) substituents arranged in pairs on neighbouring S atoms on opposite faces of the crown. The macrocyclic cation in the compound forms hydrogen bonds with the 2,4,6-trimethylbenzenesulfonate anions to create chains, which are further linked into thick two-dimensional sheets. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0108-2701 |