catena-Poly[[diaquadichloroiron(II)]-mu-1,4-dioxane-kappa2O:O']

The crystal structure of the title compound, [FeCl(2)(C(4)H(8)O(2))(H(2)O)(2)](n), contains six-coordinate Fe(II) atoms in approximately octahedral environments. The Fe(II) atoms have 1 symmetry, i.e. all pairs of identical ligands are trans. The structure consists of polymeric chains made up of dio...

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Published inActa crystallographica. Section C, Crystal structure communications Vol. 58; no. Pt 8; pp. m441 - m442
Main Authors Speer, Jr, Richard L, Pinkerton, A Alan
Format Journal Article
LanguageEnglish
Published United States 01.08.2002
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Summary:The crystal structure of the title compound, [FeCl(2)(C(4)H(8)O(2))(H(2)O)(2)](n), contains six-coordinate Fe(II) atoms in approximately octahedral environments. The Fe(II) atoms have 1 symmetry, i.e. all pairs of identical ligands are trans. The structure consists of polymeric chains made up of dioxane molecules, in the chair conformation with 1 symmetry, linking the Fe(II) centers. The chains are crosslinked by O-H...Cl hydrogen bonds.
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ISSN:0108-2701