Unexpected features of stretched Si-H...Mo beta-agostic interactions
Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of...
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| Published in | Chemical communications (Cambridge, England) no. 8; pp. 952 - 953 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
21.04.2004
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| Online Access | Get full text |
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| Abstract | Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant. |
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| AbstractList | Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant. |
| Author | Ignatov, Stanislav K Rees, Nicholas H Razuvaev, Alexei G Nikonov, Georgii I Dubberley, Stuart R Mountford, Philip |
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| Snippet | Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not... |
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| Title | Unexpected features of stretched Si-H...Mo beta-agostic interactions |
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