Unexpected features of stretched Si-H...Mo beta-agostic interactions

Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of...

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Published inChemical communications (Cambridge, England) no. 8; pp. 952 - 953
Main Authors Ignatov, Stanislav K, Rees, Nicholas H, Dubberley, Stuart R, Razuvaev, Alexei G, Mountford, Philip, Nikonov, Georgii I
Format Journal Article
LanguageEnglish
Published England 21.04.2004
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Summary:Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant.
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ISSN:1359-7345