Effect of the itinerant electron density on the magnetization and Curie temperature of Sr2FeMoO6 ceramics

• Published in: RSC advances Vol. 8; no. 51; pp. 29071 - 29077
• Main Authors: Wang, Jin-Feng, Shi, Teng-Fei, Zhuang, Zhao-Tong, Gao, Qian-Qian, Zhang, Yan-Ming
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 14.08.2018; The Royal Society of Chemistry
• Subjects: Ceramics; Chemistry; Crystal structure; Curie temperature; Electron density; Electrons; Ferromagnetism; Iron; Magnetic properties; Magnetization; Molybdenum; Perovskites; Physical properties; temperature; X-ray diffraction
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c8ra05755a

The itinerant electron density (n) near the Fermi level has a close correlation with the physical properties of Sr2FeMoO6. Two series of single-phase Sr(2−y)NayFeMoO6 (y = 0.1, 0.2, 0.3) and Sr(2−y)NayFe(1−x)Mo(1+x)O6 (y = 2x; y = 0.1, 0.2, 0.3) ceramics were specially designed and the itinerant electron density (n) of them can be artificially controlled to be: n = 1 − y and n = 1 − y + 3x = 1 + 0.5y, respectively. The corresponding crystal structure, magnetization and the ferromagnetic Curie temperature (TC) of two subjects were investigated systematically. The X-ray diffraction analysis indicates that Sr(2−y)NayFeMoO6 (y = 0.1, 0.2, 0.3) have comparable Fe/Mo anti-site defect (ASD) content in spite of decreased n. However, a drastically improved Fe/Mo ASD can be observed in Sr(2−y)NayFe(1−x)Mo(1+x)O6 (y = 2x; y = 0.1, 0.2, 0.3) caused by the intrinsic wrong occupation of normal Fe sites with excess Mo. Magnetization–magnetic field (M–H) behavior confirms that it is the Fe/Mo ASD not n that dominantly determines the magnetization properties. Interestingly, approximately when n ≤ 0.9, TC of Sr(2−y)NayFeMoO6 (y = 0.1, 0.2, 0.3) exhibits an overall increase with decreasing n, which is contrary to the TC response in electron-doped SFMO. Such abnormal TC is supposed to relate with the ratio variation of n(Mo)/n(Fe). Moreover, when n ≥ 1, TC of Sr(2−y)NayFe(1−x)Mo(1+x)O6 (y = 2x; y = 0.3) exhibits a considerable rise of about 75 K over that of Sr(2−y)NayFe(1−x)Mo(1+x)O6 (y = 2x; y = 0.1), resulting from improved n caused by introducing excess Mo into Sr(2−y)NayFeMoO6. Maybe, our work can provide an effective strategy to artificially control n and ferromagnetic TC accordingly, and provoke further investigation on the FeMo-baseddouble perovskites.