Design and Synthesis of Layered Na2Ti3O7 and Tunnel Na2Ti6O13 Hybrid Structures with Enhanced Electrochemical Behavior for Sodium‐Ion Batteries

• Published in: Advanced science Vol. 5; no. 9; pp. 1800519 - n/a
• Main Authors: Wu, Chunjin, Hua, Weibo, Zhang, Zheng, Zhong, Benhe, Yang, Zuguang, Feng, Guilin, Xiang, Wei, Wu, Zhenguo, Guo, Xiaodong
• Format: Journal Article
• Language: English
• Published: Hoboken John Wiley and Sons Inc 01.09.2018
• Subjects: Communication; Communications; hybrid structures; reaction dynamics; sodium ion batteries; sodium titanates; synergetic effects
• ISSN: 2198-3844; 2198-3844
• DOI: 10.1002/advs.201800519

A novel complementary approach for promising anode materials is proposed. Sodium titanates with layered Na2Ti3O7 and tunnel Na2Ti6O13 hybrid structure are presented, fabricated, and characterized. The hybrid sample exhibits excellent cycling stability and superior rate performance by the inhibition of layered phase transformation and synergetic effect. The structural evolution, reaction mechanism, and reaction dynamics of hybrid electrodes during the sodium insertion/desertion process are carefully investigated. In situ synchrotron X‐ray powder diffraction (SXRD) characterization is performed and the result indicates that Na+ inserts into tunnel structure with occurring solid solution reaction and intercalates into Na2Ti3O7 structure with appearing a phase transition in a low voltage. The reaction dynamics reveals that sodium ion diffusion of tunnel Na2Ti6O13 is faster than that of layered Na2Ti3O7. The synergetic complementary properties are significantly conductive to enhance electrochemical behavior of hybrid structure. This study provides a promising candidate anode for advanced sodium ion batteries (SIBs). The methodology reported utilizes the complementary properties and synergetic effect of layered‐tunnel hybrid structures to break the limitations and offset the deficiency of the respective components. The hybrid electrodes delivered 50.57 mAh g−1 at 400 mA g−1 with excellent cycling stability up to 1800 cycles and a Coulombic efficiency of 100%.