Homogeneous Transition-Metal Catalyzed C–N Activation
Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N bonds, it was mainly restricted to diazonium salts (Ar‐N2X), ammonium salts, triazenes, and imidazoles. This chapter presents a review of tr...
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| Published in | Homogeneous Catalysis for Unreactive Bond Activation pp. 269 - 316 |
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| Main Author | |
| Format | Book Chapter |
| Language | English |
| Published |
United States
John Wiley & Sons, Incorporated
2014
Wiley John Wiley & Sons, Inc |
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| Online Access | Get full text |
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| Abstract | Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N bonds, it was mainly restricted to diazonium salts (Ar‐N2X), ammonium salts, triazenes, and imidazoles. This chapter presents a review of transition‐metal‐catalyzed C‐N bond cleavage reactions, with particular emphasis on the reaction conditions, including transition‐metal‐catalysts, bases, and side reactions for achieving selective coupling. It summarizes the impressive development of the transition‐metal‐catalyzed C‐N activation in synthetic methodology. The authors hope that this short review will inspire the synthetic community to continue the search for new C‐N reactions. |
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| AbstractList | Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N bonds, it was mainly restricted to diazonium salts (Ar‐N2X), ammonium salts, triazenes, and imidazoles. This chapter presents a review of transition‐metal‐catalyzed C‐N bond cleavage reactions, with particular emphasis on the reaction conditions, including transition‐metal‐catalysts, bases, and side reactions for achieving selective coupling. It summarizes the impressive development of the transition‐metal‐catalyzed C‐N activation in synthetic methodology. The authors hope that this short review will inspire the synthetic community to continue the search for new C‐N reactions. |
| Author | Wan, Xiao‐Bing |
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| Copyright | Copyright © 2015 John Wiley & Sons, Inc. |
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| Editor | Shi, Zhang-Jie |
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| PublicationTitle | Homogeneous Catalysis for Unreactive Bond Activation |
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| Snippet | Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N... |
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| StartPage | 269 |
| SubjectTerms | bases C‐N bonds organometallic chemistry reaction conditions selective coupling side reactions synthetic methodology transition‐metal‐catalyzed C‐N activation |
| Title | Homogeneous Transition-Metal Catalyzed C–N Activation |
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