Homogeneous Transition-Metal Catalyzed C–N Activation

Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N bonds, it was mainly restricted to diazonium salts (Ar‐N2X), ammonium salts, triazenes, and imidazoles. This chapter presents a review of tr...

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Bibliographic Details
Published inHomogeneous Catalysis for Unreactive Bond Activation pp. 269 - 316
Main Author Wan, Xiao‐Bing
Format Book Chapter
LanguageEnglish
Published United States John Wiley & Sons, Incorporated 2014
Wiley
John Wiley & Sons, Inc
Subjects
bases
C‐N bonds
organometallic chemistry
reaction conditions
selective coupling
side reactions
synthetic methodology
transition‐metal‐catalyzed C‐N activation
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Summary:Recently, transition‐metal‐catalyzed C‐N bond cleavage has become an interesting research subject in organometallic chemistry. For the functionalization of C‐N bonds, it was mainly restricted to diazonium salts (Ar‐N2X), ammonium salts, triazenes, and imidazoles. This chapter presents a review of transition‐metal‐catalyzed C‐N bond cleavage reactions, with particular emphasis on the reaction conditions, including transition‐metal‐catalysts, bases, and side reactions for achieving selective coupling. It summarizes the impressive development of the transition‐metal‐catalyzed C‐N activation in synthetic methodology. The authors hope that this short review will inspire the synthetic community to continue the search for new C‐N reactions.
ISBN:9781118452233
1118452232
9781118788981
1118788982
DOI:10.1002/9781118788981.ch3