Pseudocapacitance‐Induced Synaptic Plasticity of Tribo‐Phototronic Effect Between Ionic Liquid and 2D MoS2

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 20; no. 11; pp. e2304988 - n/a
• Main Authors: Ahmadi, Ribwar, Abnavi, Amin, Hasani, Amirhossein, Ghanbari, Hamidreza, Mohammadzadeh, Mohammad Reza, Fawzy, Mirette, Kabir, Fahmid, Adachi, Michael M.
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.03.2024
• Subjects: Circuits; Contact angle; Deionization; Electric contacts; Electric potential; Electrochemistry; Energy harvesting; Ion adsorption; Ion concentration; Ionic liquids; Light; Liquid-solid interfaces; liquid–solid interface; Luminous intensity; Molybdenum disulfide; MoS2; pseudocapacitance; synaptic plasticity; triboelectric; Voltage
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.202304988

Contact‐induced electrification, commonly referred to as triboelectrification, is the subject of extensive investigation at liquid–solid interfaces due to its wide range of applications in electrochemistry, energy harvesting, and sensors. This study examines the triboelectric between an ionic liquid and 2D MoS2 under light illumination. Notably, when a liquid droplet slides across the MoS2 surface, an increase in the generated current and voltage is observed in the forward direction, while a decrease is observed in the reverse direction. This suggests a memory‐like tribo‐phototronic effect between ionic liquid and 2D MoS2. The underlying mechanism behind this tribo‐phototronic synaptic plasticity is proposed to be ion adsorption/desorption processes resulting from pseudocapacitive deionization/ionization at the liquid–MoS2 interface. This explanation is supported by the equivalent electrical circuit modeling, contact angle measurements, and electronic band diagrams. Furthermore, the influence of various factors such as velocity, step size, light wavelength and intensity, ion concentration, and bias voltage is thoroughly investigated. The artificial synaptic plasticity arising from this phenomenon exhibits significant synaptic features, including potentiation/inhibition, paired‐pulse facilitation/depression, and short‐term memory (STM) to long‐term memory (LTM) transition. This research opens up promising avenues for the development of synaptic memory systems and intelligent sensing applications based on liquid–solid interfaces. An optomechanical synaptic device based on the memory‐like tribe‐phototronic response of ionic liquid and 2D MoS2 is reported. This intriguing behavior arises from pseudocapacitance induced by ion adsorption and desorption at the liquid–MoS2 interface and opens up new opportunities in neuromorphic computing based on liquid–solid interfaces.