Robust Pseudocapacitive Sodium Cation Intercalation Induced by Cobalt Vacancies at Atomically Thin Co1−xSe2/Graphene Heterostructure for Sodium‐Ion Batteries
Electronic structure engineering on electrode materials could bring in a new mechanism to achieve high energy and high power densities in sodium ion batteries. Herein, we design and create Co vacancies at the interface of atomically thin CoSe2/graphene heterostructure and obtain Co1−xSe2/graphene he...
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Published in | Angewandte Chemie International Edition Vol. 60; no. 34; pp. 18830 - 18837 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley Subscription Services, Inc
16.08.2021
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Edition | International ed. in English |
Subjects | |
Online Access | Get full text |
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Summary: | Electronic structure engineering on electrode materials could bring in a new mechanism to achieve high energy and high power densities in sodium ion batteries. Herein, we design and create Co vacancies at the interface of atomically thin CoSe2/graphene heterostructure and obtain Co1−xSe2/graphene heterostructure electrode materials that facilitate significant Na+ intercalation pseudocapacitance. Density functional theory (DFT) calculation suggests that the Na+ adsorption energy is dramatically increased, and the Na+ diffusion barrier is remarkably reduced due to the introduction of Co vacancy. The optimized electrode delivers a superior capacity of 673.6 mAh g−1 at 0.1 C, excellent rate capability of 576.5 mAh g−1 at 2.0 C and ultra‐long life up to 2000 cycles. Kinetics analysis indicates that the enhanced Na+ storage is mainly attributed to the intercalation pseudocapacitance induced by Co vacancies. This work suggests that the creation of cation vacancy could bestow heterostructured electrode materials with pseudocapacitive Na+ intercalation for high‐capacity and high‐rate energy storage.
The Co vacancies (VCo) at the interface of Co1−xSe2/graphene (GE) afford strong adsorption of Na+ and a low Na+ diffusion energy barrier to facilitate rapid intercalation/deintercalation of Na+ ions giving remarkable pseudocapacitance. The as‐prepared Co1−xSe2/GE‐based sodium ion batteries deliver high specific/rate capacity performance and exceptional cycling performance. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.202106857 |