Chemically Exfoliated VSe2 Monolayers with Room‐Temperature Ferromagnetism

• Published in: Advanced materials (Weinheim) Vol. 31; no. 40; pp. e1903779 - n/a
• Main Authors: Yu, Wei, Li, Jing, Herng, Tun Seng, Wang, Zishen, Zhao, Xiaoxu, Chi, Xiao, Fu, Wei, Abdelwahab, Ibrahim, Zhou, Jun, Dan, Jiadong, Chen, Zhongxin, Chen, Zhi, Li, Zejun, Lu, Jiong, Pennycook, Stephen J., Feng, Yuan Ping, Ding, Jun, Loh, Kian Ping
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.10.2019
• Subjects: 2D ferromagnetism; chemical exfoliation; covalent passivation; Density functional theory; Dichroism; Exfoliation; Ferromagnetic materials; Flakes; Magnetic fields; Magnetism; Materials science; Monolayers; Organic chemistry; Room temperature; Superconducting quantum interference devices; vacancy enhanced ferromagnetism; VSe2 monolayers
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.201903779

Among van der Waals layered ferromagnets, monolayer vanadium diselenide (VSe2) stands out due to its robust ferromagnetism. However, the exfoliation of monolayer VSe2 is challenging, not least because the monolayer flake is extremely unstable in air. Using an electrochemical exfoliation approach with organic cations as the intercalants, monolayer 1T‐VSe2 flakes are successfully obtained from the bulk crystal at high yield. Thiol molecules are further introduced onto the VSe2 surface to passivate the exfoliated flakes, which improves the air stability of the flakes for subsequent characterizations. Room‐temperature ferromagnetism is confirmed on the exfoliated 2D VSe2 flakes using a superconducting quantum interference device (SQUID), X‐ray magnetic circular dichroism (XMCD), and magnetic force microscopy (MFM), where the monolayer flake displays the strongest ferromagnetic properties. Se vacancies, which can be ubiquitous in such materials, also contribute to the ferromagnetism of VSe2, although density functional theory (DFT) calculations show that such effect can be minimized by physisorbed oxygen molecules or covalently bound thiol molecules. Large‐size 1T‐VSe2 monolayers are successfully produced at high yield by electrochemical exfoliation of bulk crystal. To guard against air‐induced degradation, thiol molecules are introduced to passivate the VSe2 flakes, allowing the observation of robust room‐temperature ferromagnetism in monolayer VSe2.