Palladium-catalyzed aryl-aryl bond formation through double C-H activation

Aryl-aryl bond formation constitutes one of the most important subjects in organic synthesis. The recently developed direct arylation reactions for the formation of aryl-aryl bond have emerged as very attractive alternatives to traditional cross-coupling reactions. Particularly, the direct arylation...

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Bibliographic Details
Published inTopics in current chemistry Vol. 292; p. 165
Main Authors You, Shu-Li, Xia, Ji-Bao
Format Journal Article
LanguageEnglish
Published Germany 01.01.2010
Subjects
Catalysis
Chemistry, Organic - methods
Hydrocarbons, Aromatic - chemical synthesis
Hydrogen - chemistry
Oxidative Coupling
Oxygen - chemistry
Palladium - chemistry
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Summary:Aryl-aryl bond formation constitutes one of the most important subjects in organic synthesis. The recently developed direct arylation reactions for the formation of aryl-aryl bond have emerged as very attractive alternatives to traditional cross-coupling reactions. Particularly, the direct arylation through double C-H activation using the simple arenes as both coupling partners is a highly economic and attractive method. In this chapter, the recent progress of Pd-catalyzed aryl-aryl oxidative coupling reactions through double C-H activation is presented.
ISSN:0340-1022
DOI:10.1007/128_2009_18