Nanocomposites of 2D-MoS2 nanosheets with the metal-organic framework, ZIF-8

The nanocomposites of MoS2 nanosheets with the metal-organic framework, ZIF-8, have been synthesized starting with the layers of 1T-MoS2 generated by Li intercalation of bulk MoS2, followed by exfoliation. The nanocomposites contain the Zn-S bond and exhibit reasonably high surface areas. They exhib...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 45; no. 35; pp. 13810 - 13816
Main Authors Pramoda, K, Kaur, Manjodh, Gupta, Uttam, Rao, C N R
Format Journal Article
LanguageEnglish
Published England 21.09.2016
Subjects
Bonding
Carbon dioxide
Metal-organic frameworks
Molybdenum disulfide
Nanocomposites
Nanostructure
Surface area
Uptakes
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Summary:The nanocomposites of MoS2 nanosheets with the metal-organic framework, ZIF-8, have been synthesized starting with the layers of 1T-MoS2 generated by Li intercalation of bulk MoS2, followed by exfoliation. The nanocomposites contain the Zn-S bond and exhibit reasonably high surface areas. They exhibit CO2 uptake higher than ZIF-8. Heating the nanocomposites to 900 °C under a N2 atmosphere yields MoS2-ZnS nanocomposites which show good activity for the visible-light induced hydrogen evolution reaction.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt02667b