Enhanced selective adsorption of CO2 on nitrogen-doped porous carbon monoliths derived from IRMOF-3

The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO2 compared to pristine IRMOF-3. The transformation from the microporo...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 52; no. 63; pp. 9757 - 9760
Main Authors Ding, Shunmin, Dong, Qiaoling, Hu, Jingwei, Xiao, Weiming, Liu, Xiaohui, Liao, Lieqiang, Zhang, Ning
Format Journal Article
LanguageEnglish
Published England 28.07.2016
Subjects
Activation
Carbon
Carbon dioxide
Carbonization
Nitrogen
Pathways
Selective adsorption
Transformations
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Summary:The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO2 compared to pristine IRMOF-3. The transformation from the microporous structure to the meso-macroporous structure opens the pathway for CO2 to more easily access the nitrogen anchors.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc04416f