Dicyanovinylene-Substituted Oligothiophenes for Organic Solar Cells

We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships, which are important for materials design. We demonstrate the influence of those structural changes on the processing ability, energy levels,...

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Published inElementary Processes in Organic Photovoltaics Vol. 272; pp. 51 - 75
Main Authors Koerner, Christian, Ziehlke, Hannah, Fitzner, Roland, Riede, Moritz, Mishra, Amaresh, Bäuerle, Peter, Leo, Karl
Format Book Chapter
LanguageEnglish
Published Switzerland Springer International Publishing AG 01.01.2017
Springer International Publishing
SeriesAdvances in Polymer Science
Subjects
Alternative & renewable energy sources & technology
Charge carrier generation
Electronic devices & materials
Multijunction
Oligothiophene
Photoinduced absorption
Polymer chemistry
Small molecule
Structure-property relationships
Triplet exciton
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Abstract We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships, which are important for materials design. We demonstrate the influence of those structural changes on the processing ability, energy levels, optical properties, thin-film morphology, and charge transport. Furthermore, we give a detailed picture of the microscopic processes between photon absorption and charge carrier generation, in particular, the importance of triplet exciton losses and a relationship between the yield of charge carrier generation and macroscopic charge-transport properties.
AbstractList We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships, which are important for materials design. We demonstrate the influence of those structural changes on the processing ability, energy levels, optical properties, thin-film morphology, and charge transport. Furthermore, we give a detailed picture of the microscopic processes between photon absorption and charge carrier generation, in particular, the importance of triplet exciton losses and a relationship between the yield of charge carrier generation and macroscopic charge-transport properties.
Author Fitzner, Roland
Riede, Moritz
Koerner, Christian
Bäuerle, Peter
Mishra, Amaresh
Leo, Karl
Ziehlke, Hannah
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Snippet We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships,...
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StartPage 51
SubjectTerms Alternative & renewable energy sources & technology
Charge carrier generation
Electronic devices & materials
Multijunction
Oligothiophene
Photoinduced absorption
Polymer chemistry
Small molecule
Structure-property relationships
Triplet exciton
Title Dicyanovinylene-Substituted Oligothiophenes for Organic Solar Cells
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