Dicyanovinylene-Substituted Oligothiophenes for Organic Solar Cells

We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships, which are important for materials design. We demonstrate the influence of those structural changes on the processing ability, energy levels,...

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Bibliographic Details
Published inElementary Processes in Organic Photovoltaics Vol. 272; pp. 51 - 75
Main Authors Koerner, Christian, Ziehlke, Hannah, Fitzner, Roland, Riede, Moritz, Mishra, Amaresh, Bäuerle, Peter, Leo, Karl
Format Book Chapter
LanguageEnglish
Published Switzerland Springer International Publishing AG 01.01.2017
Springer International Publishing
SeriesAdvances in Polymer Science
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Summary:We investigate dicyanovinyl-substituted oligothiophene derivatives as absorber materials in organic solar cells. We determine structure–property relationships, which are important for materials design. We demonstrate the influence of those structural changes on the processing ability, energy levels, optical properties, thin-film morphology, and charge transport. Furthermore, we give a detailed picture of the microscopic processes between photon absorption and charge carrier generation, in particular, the importance of triplet exciton losses and a relationship between the yield of charge carrier generation and macroscopic charge-transport properties.
ISBN:3319283367
9783319283364
ISSN:0065-3195
1436-5030
DOI:10.1007/978-3-319-28338-8_3