Characterizations of REE:Tb2O3 Magneto‐Optical Ceramics

• Published in: physica status solidi (b) Vol. 257; no. 8
• Main Authors: Balabanov, Stanislav S., Permin, Dmitry A., Rostokina, Elena Ye, Palashov, Oleg V., Snetkov, Ilya L.
• Format: Journal Article
• Language: English
• Published: 01.08.2020
• Subjects: hot pressing; magneto-optics; terbium oxide; transparent ceramics
• ISSN: 0370-1972; 1521-3951
• DOI: 10.1002/pssb.201900474

The magneto‐optical ceramics of terbium oxide doped with different rare earth elements (REE) REE:Tb2O3 (REE—Y3+, Lu3+, Sc3+, Ce3+, Dy3+, Ho3+, Yb3+, Nd3+) are successfully fabricated by hot pressing using powders obtained by the self‐propagating high‐temperature synthesis (SHS) method. The prepared REE:Tb2O3 ceramics have good optical quality and magneto‐optical properties. The in‐line transmittance of Tb2O3 ceramics doped with REE except Sc3+ is close to undoped terbium oxide, especially in the long‐wavelength region. The Verdet constant of the REE:Tb2O3 samples considered at 633 nm is about 3.3 and 2.6 times higher in absolute value than that of the commercial terbium–gallium garnet (TGG) single crystal and terbium–aluminum garnet (TAG) ceramics, respectively. It is noted that REE (except Yb3+ and Nd3+) doping only slightly increases the Verdet constant of pure Tb2O3 (when the content of terbium ions in the optical element is taken into consideration in the calculation). The dilution of the Tb2O3 matrix with REE in relatively high concentrations leads to a decrease in the absolute value of the Verdet constant. Rare earth elements in terbium oxide ceramics increase its Verdet constant, normalized to the concentration of terbium ions. However, the Verdet constant absolute value decreases due to the dilution of the Tb2O3 matrix with rare earth elements. Thus, pure terbium oxide has a record Verdet value among the studied materials.