Photoluminescence and X‐Ray‐Induced Luminescence Behavior of Sm2O3‐Doped Oxyfluoroborate Scintillating Glass for Radiation Detecting Material

• Published in: Physica status solidi. A, Applications and materials science Vol. 220; no. 10
• Main Authors: Meejitpaisan, Piyachat, Doddoji, Ramachari, Kim, Hong Joo, Jayasankar, Chalicheemalapalli K., Kaewkhao, Jakrapong
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.05.2023
• Subjects: absorption (UV–visible–NIR); Absorption spectra; Aluminum fluorides; BGO (crystal); Boron oxides; color coordinates; Color temperature; Cross-sections; decay curves; Energy transfer; Excitation spectra; excitation–emission spectra; Glass; Luminescence; Parameters; Photoluminescence; Quantum efficiency; Samarium; Scintillation; Scintillation counters; Stimulated emission; X-ray-irradiated luminescence
• ISSN: 1862-6300; 1862-6319
• DOI: 10.1002/pssa.202200441

Various concentrations of samarium (Sm3+) ion‐activated oxyfluoroborate (ANCB:AlF3‐NaF‐CaF2‐B2O3) glasses are fabricated for its applications in red‐emitting lasers and scintillators. From the optical absorption spectrum, Ω2,4,6 intensity parameters and several radiative parameters along with the high value of absorption (2.96 × 10−21 cm2) and emission (14.13 × 10−22 cm2) cross sections are calculated. By stimulating at 403 nm, a transition corresponding to 4G5/2 → 6H7/2 (596 nm) is very intense and emits orange‐reddish luminescence of Sm3+ ion in ANCB glasses. The decay curves are fit to the Inokuti–Hirayama (I–H) model to determine the energy transfer in Sm3+: ANCB glasses. The X‐ray‐excited luminescence (XEL) spectra are determined with an X‐ray source by supplying the voltage of 50 kV and current 30 mA. The lasing parameters like stimulated emission cross section (14.13 × 10−22 cm2), optical gain (30.52 × 10−22 cm2 s), and quantum efficiency (80%) are found to be high for the 4G5/2 → 6H9/2 transition of Sm3+ ions. The quality of the emitted red light for the ANCBSm0.5 glass is calculated in terms of the (x, y) color coordinates and correlated color temperatures (CCT < 3000 K). The integral scintillation efficiency of glasses shows the maximum value of 23% in comparison with Bi4Ge3O12 scintillation crystal. Oxyfluoroborate glasses doped with the samarium ion (Sm3+:ANCB) are prepared and their luminescence properties are examined upon 403 nm and X‐ray irradiation. These glasses emit light in the orange‐red region with the (0.5889, 0.4098) color coordinates and show the scintillation efficiency of 23%, which can be applied potentially in radiation‐detecting material applications.