No‐organic solvent, no‐fluorinated waterborne superhydrophobic coatings based on SiO2 and IBTS

• Published in: Journal of applied polymer science Vol. 141; no. 25
• Main Authors: Yang, Yu, Zhang, Hai, Cao, Lei, Meng, Weikai, Ma, Xinru, Li, Xinzi, Zheng, Junping, Liu, Xiaofei
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 05.06.2024; Wiley Subscription Services, Inc
• Subjects: Abrasion resistance; Acrylic resins; Coatings; Contact angle; crosslinking; Fluorine; Hydrophobic surfaces; Hydrophobicity; Phenolic resins; Physical properties; polyurethane; Polyurethane resins; Silicon dioxide; Solvents; Spraying; Water resistance
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.55537

Waterborne superhydrophobic coatings have attracted widespread attention. However, organic solvents, fluorine‐containing compounds, and complex operational technologies hinder superhydrophobic coatings development severely. Herein, A simple method of preparing water‐based superhydrophobic coatings by one‐step spraying without organic solvent and fluorine is reported. The particles of silicon dioxide (SiO2) was modified by isobutyltriethoxysilane (IBTS), then combined with waterborne acrylic polyurethane (WPUA) and phenolic resin (PF), baked at 110°C to fabricate superhydrophobic coatings. According to the contact Angle (CA), hardness, adhesion, and other parameters, the ratio of SiO2 and PF of the composite coatings was optimized. Results showed that the superhydrophobicity and physical properties of the coating are the most exceptional at the content of SiO2 is 0.6 g, and the PF is 25%. In addition, related experimental results show that the coatings have good water resistance and self‐cleaning ability, the special nano/micro structure of the coatings also endows it excellent abrasion resistance. Exceptional hydrophobicity and physical properties meeting the actual application conditions of superhydrophobic coatings. Therefore, the simple method for preparing superhydrophobic coatings has great application prospects. Schematic flow diagram and performance characteristics for the preparation of aqueous superhydrophobic coatings based on IBTS and SiO2.