Photodynamic properties of tungsten iodide clusters incorporated into silicone: A2[M6I8L6]@silicone

The light-induced antibacterial and antifungal properties of A2[M6I8L6] with M = Mo and W, A = organic cation, L = ligand have been studied. The photoactive compounds (TBA)2[W6I8(C7H7SO3)6] and (TBA)2[W6I8(COOCF3)6] have been incorporated into a permeable silicone matrix and were measured for their...

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Bibliographic Details
Published inRSC advances Vol. 10; no. 37; pp. 22257 - 22263
Main Authors Hummel, Thorsten, Dutczak, Danuta, Alekseev, Alexander Y, Adamenko, Lyubov S, Shestopalov, Michael A, Mironov, Yuri V, Enseling, David, Jüstel, Thomas, Meyer, Hans-Jürgen
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 10.06.2020
The Royal Society of Chemistry
Subjects
Chemistry
Clusters
Fungicides
Microorganisms
Tungsten
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Summary:The light-induced antibacterial and antifungal properties of A2[M6I8L6] with M = Mo and W, A = organic cation, L = ligand have been studied. The photoactive compounds (TBA)2[W6I8(C7H7SO3)6] and (TBA)2[W6I8(COOCF3)6] have been incorporated into a permeable silicone matrix and were measured for their application in the decomposition of multi-resistant bioactive species (hospital germs) such as S. aureus and P. aeruginosa as well as fungi. In addition, we present a new high volume synthesis route for these types of cluster compounds departing from the soluble compound W6I22.
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ISSN:2046-2069
DOI:10.1039/d0ra04280c