Diffusion of cadmium chloride in aqueous solutions at physiological temperature 310.15 K

Mutual diffusion coefficients (interdiffusion coefficients) of cadmium (II) chloride in water at T = 310.15 K at concentrations between 0.001 molADTdm-3 and 0.400 molADTdm-3 have been determined, using the Taylor technique. The results are discussed on the basis of Nernst, and Onsager and Fuossa the...

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Published inThe Journal of chemical thermodynamics Vol. 57; pp. 404 - 407
Main Authors RIBEIRO, Ana C. F, GOMES, Joselaine C. S, VERISSIMO, Luis M. P, ROMERO, Carmen, BLANCO, Luis H, ESTESO, Miguel A
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier 01.02.2013
Subjects
Aqueous solutions
Cadmium
Chemical thermodynamics
Chemistry
Chlorides
Conductance
Diffusion
Diffusion coefficient
Equivalence
Exact sciences and technology
General and physical chemistry
General. Theory
Thermodynamics
Electrolytes
Transport properties
Physiological temperature
Solutions
Diffusion
Cadmium chloride
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Summary:Mutual diffusion coefficients (interdiffusion coefficients) of cadmium (II) chloride in water at T = 310.15 K at concentrations between 0.001 molADTdm-3 and 0.400 molADTdm-3 have been determined, using the Taylor technique. The results are discussed on the basis of Nernst, and Onsager and Fuossa theories, taking into account different phenomena such as electrophoretic and thermodynamic effects. Using such results, the equivalent conductance at infinitesimal concentration of the cadmium (II) ion in these solutions at T = 310.15 K has been estimated.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0021-9614
1096-3626
DOI:10.1016/j.jct.2012.09.011