Insights into interfacial mechanisms: CsPbBr3 nanocrystals as sustainable photocatalysts for primary amine oxidation

CsPbBr3 nanocrystals (NCs) employed as a photocatalyst resulted in efficient benzylamine oxidation under oxygen atmosphere. Improved reaction yields stem from favorable –NH2 functional group interactions on the NC surface, while additional interactions with –OMe or –SMe functional groups post-produc...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 60; no. 17; pp. 2365 - 2368
Main Authors Ahlawat, Monika, Vishal Govind Rao
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 22.02.2024
Subjects
Functional groups
Nanocrystals
Oxidation
Photocatalysts
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Summary:CsPbBr3 nanocrystals (NCs) employed as a photocatalyst resulted in efficient benzylamine oxidation under oxygen atmosphere. Improved reaction yields stem from favorable –NH2 functional group interactions on the NC surface, while additional interactions with –OMe or –SMe functional groups post-product formation result in lower yields. These insights into interfacial interactions and mechanistic aspects advance sustainable chemical transformations through cost-effective and recyclable CsPbBr3 NC-catalyzed primary amine oxidation.
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ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc05725a