Inorganic acid influenced formation of Ti26 and Ti44 oxysulfate clusters with toroidal and capsule structures

We herein report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters by ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO42−vs. pseudo-tetrahedral PO33−) shows an interesting influence on cluster structure formation.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 51; no. 16; pp. 6162 - 6165
Main Authors Chintakrinda, Kalpana, Nagaraju Narayanam, Guang-Hui Chen, Wang, Fei, Zhang, Jian, Zhang, Lei
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 20.04.2022
Subjects
Clusters
Inorganic acids
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Summary:We herein report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters by ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO42−vs. pseudo-tetrahedral PO33−) shows an interesting influence on cluster structure formation.
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ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d2dt00119e