Evaluating the efficacy of nanosized CuZnAl and CuZnZr mixed oxides for electrocatalytic CO2 reduction

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 16; pp. 5155 - 5168
• Main Authors: Mostafa, Mohamed Mokhtar M, Li, Yining, Halawani, Wael, Narasimharao, Katabathini, Mohamed Abdel Salam, Alshehri, Abdulmohsen A, Khdary, Nezar H, Al-Faifi, Sulaiman, Gu, Lin, Abhishek Dutta Chowdhury
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 25.04.2023
• Subjects: Aluminum oxide; Annealing; Carbon dioxide; Chemical reduction; Copper; Effectiveness; Mixed oxides; Zinc oxide; Zirconium dioxide
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt04111a

The increased awareness of carbon management has prompted the scientific community towards delivering sustainable catalytic technologies, preferably from CO2. Copper-based multifunctional catalysts are the most frequently used for thermal hydrogenation and electrocatalytic reduction of CO2 (CO2R) processes. To improve the understanding and efficacy of these materials for the CO2R reaction, Cu–Zn oxides combined with Al2O3 and ZrO2 were synthesized by the coprecipitation method and annealed at 500 °C, 600 °C, and 700 °C (i.e., Cu/ZnO/Al2O3-x and Cu/ZnO/ZrO2 systems-x, where x is the annealing temperature) to tune their multi-functionality. We demonstrate that the composition of Cu–Zn oxides and pretreatment temperature impact the electrocatalytic CO2R performance, where CuZnZr-600 and CuZnAl-700 materials are superior. Different characterization tools were employed to rationalize the results described in this work, which could provide a way to design an efficient catalytic system for the CO2R process.