An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K)

An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142− anion are proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13− and B10H15− intermediates were detected....

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 52; no. 47; pp. 17684 - 17688
Main Authors Xi-Meng, Chen, Xing-Chao, Yu, Jing-Xian Chi, Yi, Jing, Wang, Hongju, Zhang, Na, Zhang, Chen, Yi-Wen, Ge, Chen, Xuenian
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 05.12.2023
Subjects
Anions
Synthesis
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Summary:An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142− anion are proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13− and B10H15− intermediates were detected.
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ISSN:1477-9226
1477-9234
DOI:10.1039/d3dt03403h