Synergistic effect of K and Zn on Fe-based catalysts for efficient CO2 hydrogenation

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 6; pp. 2526 - 2533
• Main Authors: Jia-Min Lyu, Shen, Yu, Liu, Zhan, He-You, Du, Ming-Hui, Sun, Chun-Mu, Guo, Yi-Long, Wang, Li, Yu, Li-Hua, Chen, Bao-Lian, Su
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 06.02.2024
• Subjects: Adsorption; Alkenes; Carbon dioxide; Cascade chemical reactions; Catalysts; Catalytic converters; Hydrogenation; Iron; Selectivity; Sustainable development; Synergistic effect; Zinc
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d3dt03913g

Excessive emission of CO2 into the atmosphere has severely impacted the global ecological environment. Converting CO2 into valuable chemicals and fuels is of great significance for sustainable development. However, low activity and undesirable selectivity often result from the inherent inertness of CO2. Herein, K- or/and Zn-modified Fe-based catalysts were prepared by an incipient-wetness impregnation method for CO2 hydrogenation via a cascade reaction. The results indicate that K species exist as K2O while Zn species exist as ZnFe2O4. In the CO2 hydrogenation pathway, K2O facilitates the adsorption of CO2 and restrains the adsorption of H2, accelerating the transformation of CO2 into C2–C4 olefins rather than paraffins while Zn species promote the dispersion of Fe species, leading to improved activity. Synergistically, a K- and Zn-modified Fe-based catalyst (2Zn–10K–Fe/Al) shows excellent catalytic CO2 hydrogenation activity, achieving a CO2 conversion of 77% which is 1.8 times that (42%) of the unmodified Fe-based catalyst (Fe/Al). Our catalyst also shows a significantly promoted selectivity to C2–C4 olefins of 17% in comparison with the Fe/Al catalyst (0%). It is envisioned that such a binary effect of elements might contribute to the low-cost and industrial production of Fe-based catalysts for selective CO2 conversion.