Poly[N-Heterylmethyl(Propyl, Butyl)](Organo)Siloxanes -- New Modifiers for Chemical Fibres and Cloth

A method was developed for production of chemically modified fibres containing covalently bound poly[N-heterylmethyl(propyl,butyl)](organo)siloxanes on the surface. These modifiers are of great interest as specific reagents and catalysts in organic and organometallic synthesis, sorbents for precious...

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Published inFibre chemistry Vol. 33; no. 6; pp. 452 - 454
Main Authors Izmailov, B A, Bochkarev, N E, Budkin, N A
Format Journal Article
LanguageEnglish
Published New York Springer Nature B.V 01.11.2001
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Summary:A method was developed for production of chemically modified fibres containing covalently bound poly[N-heterylmethyl(propyl,butyl)](organo)siloxanes on the surface. These modifiers are of great interest as specific reagents and catalysts in organic and organometallic synthesis, sorbents for precious metals, and biologically active substances. The modified fibres are obtained with a high yield in the reaction of condensation of N-sodium derivatives of 3,5-dimethylpyrazole, 4-methyl-1-phenyl-3-pyrazolidone, 1, 2, 4-triazole, 2-methylindole, benzimidazole with (organo)siloxane chloromethyl(propyl,butyl)silyl groups covalently bound on the surface of the fibres. The concentration of bound groups was determined by elemental analysis. The new materials were characterized with the data from the IR spectra.[PUBLICATION ABSTRACT]
Bibliography:ObjectType-Article-2
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ISSN:0015-0541
1573-8493
DOI:10.1023/A:1015003316325