Selective modification of beta-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2(A) and C2(B) via a sulfur atom

2(A), 3(A)-Alloepithio-2(B)-sulfonyl-beta-cyclodextrin undergoes a tandem reaction to generate an unprecedented C2(A)-S-C2(B)-bridged glucosyl-3(A),6(A)-anhydroglucoside segment.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 30; pp. 3157 - 3159
Main Authors Fukudome, Makoto, Yoshikawa, Kazuki, Koga, Kazutaka, Yuan, De-Qi, Fujita, Kahee
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 14.08.2007
Subjects
beta-Cyclodextrins - chemistry
Chemistry
Chemistry, Multidisciplinary
Glucosides - chemistry
Nuclear Magnetic Resonance, Biomolecular
Physical Sciences
Science & Technology
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Summary:2(A), 3(A)-Alloepithio-2(B)-sulfonyl-beta-cyclodextrin undergoes a tandem reaction to generate an unprecedented C2(A)-S-C2(B)-bridged glucosyl-3(A),6(A)-anhydroglucoside segment.
ISSN:1359-7345
1364-548X
DOI:10.1039/b703943c