Towards ruthenium(II) polypyridine complexes with prolonged and predetermined excited state lifetimes

The excited state lifetime of a Ru(bpy)3-motif is linearly related to the number of appended pyrenyl chromophores, but independent of connectivity; values for nine complexes range from 0.8 to 18.1 microseconds.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 6; pp. 602 - 603
Main Authors McClenaghan, Nathan D, Barigelletti, Francesco, Maubert, Béatrice, Campagna, Sebastiano
Format Journal Article
LanguageEnglish
Published England 21.03.2002
Subjects
Half-Life
Kinetics
Ligands
Luminescence
Organometallic Compounds - chemistry
Oxidation-Reduction
Pyridines - chemistry
Ruthenium - chemistry
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Summary:The excited state lifetime of a Ru(bpy)3-motif is linearly related to the number of appended pyrenyl chromophores, but independent of connectivity; values for nine complexes range from 0.8 to 18.1 microseconds.
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ISSN:1359-7345
DOI:10.1039/b110291e