HPLC separation of diastereomers of Ln(III)-ethylenepropylene-triamine-pentaacetate complexes. Direct assessment of their water exchange rate

The diastereomers of two Ln(III)-EPTPA derivatives have been separated by reversed-phase HPLC, and the water exchange rate on their Gd(III) complexes has been directly determined by 17O NMR (H5EPTPA = ethylenepropylene-triamine-pentaacetic acid).

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 21; pp. 2680 - 2681
Main Authors Burai, László, Tóth, Eva, Merbach, André E
Format Journal Article
LanguageEnglish
Published England 07.11.2003
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Summary:The diastereomers of two Ln(III)-EPTPA derivatives have been separated by reversed-phase HPLC, and the water exchange rate on their Gd(III) complexes has been directly determined by 17O NMR (H5EPTPA = ethylenepropylene-triamine-pentaacetic acid).
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ISSN:1359-7345
DOI:10.1039/b308253a