Oxy-function promoted hydroboration of conjugated dienes with controlled allylic borane rearrangement

Hydroboration of conjugated dienes is promoted by the hydroxy and methoxy groups, which also control the rearrangement of the initially produced allylic boranes.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 21; pp. 2180 - 2181
Main Authors Sugimura, T, Nishida, F, Tei, T, Morisawa, A, Tai, A, Okuyama, T
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.11.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ALCOHOLS
ORGANIC-SYNTHESIS
INTRAMOLECULAR HYDROSILATION
SILAFUNCTIONAL COMPOUNDS
CHIRAL SYNTHESIS
BRIDGE
ASYMMETRIC HYDROBORATION
CYCLIC HYDROBORATION
STEREOSELECTIVE SYNTHESIS
ORGANOBORANES
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Summary:Hydroboration of conjugated dienes is promoted by the hydroxy and methoxy groups, which also control the rearrangement of the initially produced allylic boranes.
ISSN:1359-7345
1364-548X
DOI:10.1039/b106850d