Controllable growth of bulk cubic-phase CH3NH3PbI3 single crystal with exciting room-temperature stability

To obtain bulk cubic CH3NH3PbI3, chlorobenzene was employed to regulate the CH3NH3PbI3 gamma -butyrolactone solution with high saturated solubility at room temperature and a high yield of crystal at 60 degree C. As a result, bulk cubic CH3NH3PbI3 single crystal was successfully synthesized for the f...

Full description

Saved in:
Bibliographic Details
Published inCrystEngComm Vol. 18; no. 28; pp. 5257 - 5261
Main Authors Luan, Mengyu, Song, Junling, Wei, Xiangfeng, Chen, Fang, Liu, Jiehua
Format Journal Article
LanguageEnglish
Published 01.01.2016
Subjects
Chlorobenzenes
Crystals
Phase inversion
Phase shift
Single crystals
Solubility
Stability
Online AccessGet full text

Cover

More Information
Summary:To obtain bulk cubic CH3NH3PbI3, chlorobenzene was employed to regulate the CH3NH3PbI3 gamma -butyrolactone solution with high saturated solubility at room temperature and a high yield of crystal at 60 degree C. As a result, bulk cubic CH3NH3PbI3 single crystal was successfully synthesized for the first time in mixed-solvent method at 60 degree C, which is a little higher than the tetragonal-cubic phase inversion temperature.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1466-8033
DOI:10.1039/c6ce00375c