Dielectric studies of H-bonded complexes of benzamide and nicotinamide with alcohols

The hydrogen-bonded complexes formed by benzamide and nicotinamide with alcohols in 1, 4-dioxan were studied at 303 K. The following alcohols were used: 2-butoxy ethanol, 2-ethyl hexanol, hexan-1-ol and isopropanol. The dipole moments of the complexes were determined using Huyskens method. The exces...

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Published inIndian journal of pure & applied physics Vol. 44; no. 4; pp. 339 - 344
Main Authors Sankar, U, Jeevaraj, A Kingson Solomon, Thenappan, T
Format Journal Article
LanguageEnglish
Published 01.04.2006
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Summary:The hydrogen-bonded complexes formed by benzamide and nicotinamide with alcohols in 1, 4-dioxan were studied at 303 K. The following alcohols were used: 2-butoxy ethanol, 2-ethyl hexanol, hexan-1-ol and isopropanol. The dipole moments of the complexes were determined using Huyskens method. The excess dipole moments of the complexes were obtained from bond angle data. The results show the domination of polarization effects and the non-feasibility of higher order complexations.
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ISSN:0019-5596