Effect of Latex Particles Addition on the Rheological Behavior of Concentrated Silica Suspensions Used as Cement Pastes Model Systems

The studied model silica suspensions present the same rheological as cement pastes, especially a sharp transition between a gel behaviour and a liquid behaviour when the shear stress is increased. This rheological behaviour can be explained by the percolation or the breakup of aggregates. Adding a p...

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Published inThe XVth International Congress on Rheology Part One (AIP Conference Proceedings Volume 1027, Part 1) Vol. 1027; pp. 719 - 721
Main Authors Moan, Michel, Chougnet, Alice, Audibert, Annie
Format Journal Article
LanguageEnglish
Published 01.01.2008
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Summary:The studied model silica suspensions present the same rheological as cement pastes, especially a sharp transition between a gel behaviour and a liquid behaviour when the shear stress is increased. This rheological behaviour can be explained by the percolation or the breakup of aggregates. Adding a polymer redispersible powder does not modify qualitatively this rheological behaviour. But replacing silica particles (or cement) by polymer ones induces in the gel state a decrease of the storage modulus and in the liquid state a decrease of the viscosity. The decrease of the storage modulus might be due to the lower interactions between polymer and silica particles than the ones between silica particles; the decrease of the viscosity might be linked to the fact that, as polymer particles are less hydrophilic than silica ones, they entrap less water within the aggregates.
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ISBN:0735405492
9780735405493
ISSN:0094-243X
DOI:10.1063/1.2964822