Microwave Spectrum and Structure of Methyl Nitrite

The microwave spectra of the normal species and five isotopic species of methyl nitrite, CH3ONO, have been assigned between 8 and 40 GHz. Analysis of the observed rotational constants of those isotopic species has resulted in the following bond lengths and angles as the structural parameters of cis...

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Published inNippon Kagakukai shi (1972) Vol. 1977; no. 5; p. 729
Main Authors ENDO, Kunihiko, KAMURA, Yuichi
Format Journal Article
LanguageEnglish
Japanese
Published Tokyo Japan Science and Technology Agency 01.01.1977
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Summary:The microwave spectra of the normal species and five isotopic species of methyl nitrite, CH3ONO, have been assigned between 8 and 40 GHz. Analysis of the observed rotational constants of those isotopic species has resulted in the following bond lengths and angles as the structural parameters of cis form C-0 1.430 A, 0-N 1.415 A, N.0 1.185 A, C-H (in-plane) 1.063 A, C-H (out of plane) 1.98A, LON() 115.2°, LCON 114.0°, LOCH' 1O2-.9', LOCH, 110.2°, LH0CH0 107.90.
ISSN:0369-4577
DOI:10.1246/nikkashi.1977.729