Synthesis, spectral and antimicrobial activity of [3-(4-chloro-phenoxy)-2,4-diisopropyl)-2,3,4,5-tetrahydro-1H-3l5-benzo[e][1,3,2]diazaphosphepin-3-ylidene]-alkyl-amine (Staudinger reaction
3-(4-chlorophenoxy)-2,4-diisopropyl-2,3,4,5-tetrahydro-1H-benzo[e][1,3,2]diaza-phosphepine was synthesized starting from 1,2-bis(bromomethyl)benzene by reacting with 2 equimolar isopropyl amine, one equimolar PBr3 and then one equimolar 4-chlorophenol, respectively. The Staudinger reaction of the di...
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Published in | Organic communications Vol. 2; no. 4; p. 120 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Gebze
ACG Publications
01.10.2009
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Online Access | Get full text |
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Summary: | 3-(4-chlorophenoxy)-2,4-diisopropyl-2,3,4,5-tetrahydro-1H-benzo[e][1,3,2]diaza-phosphepine was synthesized starting from 1,2-bis(bromomethyl)benzene by reacting with 2 equimolar isopropyl amine, one equimolar PBr3 and then one equimolar 4-chlorophenol, respectively. The Staudinger reaction of the diazaphphosphine with a series of alkyl azides gave the corresponding iminophosphoranes. Antibacterial activities of the synthesized iminophosphoranes were screened |
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ISSN: | 1307-6175 |